Lösung:
Es to leave The Commission two reactions to formulate:
a) H2(g) + 1/2·O2(g) → H2O(g) and
b) H2(g) + O2(g) → H2O2(g)
Respect: With this The Results with each other Compared will be can must It's The Commission on The equal to Number of Education and training H2O Responsibility. H2O2 Related!
Table of values, All of them Participants Particles are In the Gaseous State of operation:
| ΔHof(kJ·mol-1) | So(J·K-1·mol-1) |
| H2 (g) | 0 | 131 |
| O2 (g) | 0 | 205 |
| H2O (g) | -242 | 189 |
| H2O2 (g) | -136 | 233 |
- reaction a), It 's occurring H2O
Definition: ΔHoR = ∑ΔHof(Produkte) – ∑ΔHof(Edukte)
ΔHoR(H2O) = (-242) – (0 + 1/2·0) = -242 kJ/mol
ΔSoR(H2O) = (189) – (131 + 1/2·205) = -44.5 J/(mol·K)
Definition: ΔGoR = ΔHoR – T· ΔSoR
ΔGoR(H2O) = -242 – 800·-0.0445 = -206.4 kJ/mol
- reaction b), It 's occurring H2O2
Definition: ΔHoR = ∑ΔHof(Produkte) – ∑ΔHof(Edukte)
ΔHoR(H2O2) = (-136) – (0 + 1/2·0) = -136 kJ/mol
ΔSoR(H2O2) = (233) – (131 + 205) = -103 J/(mol·K)
Definition: ΔGoR = ΔHoR – T· ΔSoR
ΔGoR(H2O2) = -136 – 800·-0.103 = -53.6 kJ/mol
The calculation shows, that However, both reactions Exergonically ( ΔGoR < 0) and This means that Voluntary running I have to.. reaction a) is But almost to One Factor 4 Stronger Exergonically and will be This means that Preferably running.